水解酸化-接触氧化法处理生活污水的工艺设计

厂区生活污水有机物及悬浮颗粒含量高,可生化性好。采用水解酸化-接触氧化法(厌氧/好氧)处理生活污水,目前系统运行稳定,出水各项指标达到国家GB 8978—1996《污水综合排放标准》中二级排放标准。设计处理能力为1 500 m3/d,处理后出水进入厂区回用水池。     

Shellac-coated iron oxide nanoparticles for removal of cadmium(II) ions from aqueous solution

This study describes a new effective adsorbent for cadmium removal from aqueous solution synthesized by coating a shellac layer, a natural biodegradable and renewable resin with abundant hydroxyl and carboxylic groups, on the surface of iron oxide magnetic nanoparticles. Transmission Electron Microscopy (TEM) imaging showed shellac-coated magnetic nanoparticle (SCMN) adsorbents had a core-shell structure with a core of 20 nm and shell of 5 nm. Fourier Transform Infrared Spectroscopic analysis suggested the occurrence of reaction between carboxyl groups on the SCMN adsorbent surface and cadmium ions in aqueous solution. Kinetic data were well described by pseudo second-order model and adsorption isotherms were fitted with both Langmuir and Freundlich models with maximum adsorption capacity of 18.80 mg/g. SCMN adsorbents provided a favorable adsorption capacity under high salinity conditions, and cadmium could easily be desorbed using mild organic acid solutions at low concentration.     

沼气高值化利用与净化提纯技术

基于户用沼气池以及传统工业沼气锅炉的低附加值沼气利用方式已经不适合沼气产业规模化和商业化的发展方向,在分析我国沼气资源潜力的基础上,重点介绍了沼气制备车用压缩天然气、管道天然气、热电联产等高值化利用方式及相关标准;针对高值化利用方式,分析比较了现有的高压水洗、物理吸收、化学吸收、变压吸附、膜分离和深冷分离等几种沼气净化提纯工艺的技术及应用情况,介绍了高效沼气脱硫技术,并指出氧、氮含量源头控制的重要性。     

基于循环特性的镍氢和锂离子电池环境影响机制分析

为了了解镍氢电池和锂离子电池在生产、使用、废弃或回收过程中的环境影响,建立了一种简单快速的二次电池环境影响机制分析方法。通过生命周期评价(LCA)方法,采用Eco-indicator99体系,综合考虑电池循环容量衰减和循环次数的影响,建立了二次电池环境影响机制分析模型,并运用此模型对两种实验用二次电池(镍氢电池和锂离子电池)的环境影响机制进行了研究。结果表明:1)在所选取的两种二次电池当中,锂离子(Li-ion)电池的环境影响明显比镍氢(Ni-MH)电池的低;2)随着循环次数的增加Li-ion电池环境影响衰减比Ni-MH电池的明显,即随着使用循环次数的增加,Li-ion电池对环境的影响会降低到更多。综合来说,所选取的Li-ion电池比Ni-MH电池更具环境可持续性。文中所提出的环境影响机制分析模型同样可以应用于其他二次电池,以期为环境友好型二次电池的开发提供帮助。     

浅海跃层底质对水下声的影响研究

本文针对海底底质对水下噪声传播具有显著影响的现象,选取典型负梯度温度跃层,加载三个典型海底底质,即细砂底质、粉砂底质及黏土-粉砂底质,声波参数为固定值。试验定性分析了浅海海底底质对水下声传播的影响,仿真计算了海底底质对声传播的影响,比较分析了不同底质条件下声波的衰减差异,总结了不同底质对水下声传播影响的特点,并同行参考。     

非烟气工况下常规烟塔与改造烟塔内部结构的比较

根据流体力学理论,基于Fluent6.3.26计算平台,对常规冷却塔和改造后的排烟冷却塔进行了三维内部流场的模拟。分析非烟气工况下,两塔内部烟道布置对气流的影响,为进一步研究在工况条件下烟气、水蒸气塔内扰流与湿热蒸汽抬升作用提供理论基础。验证了改造烟塔内部烟道布置的优越性,对排烟冷却塔结构优化有一定的指导意义。     

Mechanism of lead immobilization by oxalic acid-activated phosphate rocks

Lead (Pb) chemical fixation is an important environmental aspect for human health. Phosphate rocks (PRs) were utilized as an adsorbent to remove Pb from aqueous solution. Raw PRs and oxalic acid-activated PRs (APRs) were used to investigate the effect of chemical modification on the Pb-binding capacity in the pH range 2.0-5.0. The Pb adsorption rate of all treatments above pH 3.0 reached 90%. The Pb binding on PRs and APRs was pH-independent, except at pH 2.0 in activated treatments. The X-ray diffraction analysis confirmed that the raw PRs formed cerussite after reacting with the Pb solution, whereas the APRs formed pyromorphite. The Fourier Transform Infrared spectroscopy analysis indicated that carbonate (CO₃^2-) in raw PRs and phosphate (PO₄^3-) groups in APRs played an important role in the Pb-binding process. After adsorption, anomalous block-shaped particles were observed by scanning electron microscopy with energy dispersive spectroscopy. The X-ray photoelectron spectroscopy data further indicated that both chemical and physical reactions occurred during the adsorption process according to the binding energy. Because of lower solubility of pyromorphite compared to cerussite, the APRs are more effective in immobilizing Pb than that of PRs.     

应用水培蔬菜净化滇池富营养水体分析研究

通过对福保乡水培蔬菜示范区的进出口水体中营养物质氮、磷、COD、氨氮等指标的监测数据分析,研究水培蔬菜净化滇池富营养化水体的作用、效果、水环境的改善以及由此带来的经济和景观价值。     

SBR亚硝化快速启动过程中影响因子研究

在低DO条件下对SBR反应器实现快速亚硝化的途径及影响因素进行研究.控制反应器主要参数为：DO 0.15～0.40mg/L,pH值7.52～8.30,温度22.3～27.1℃,曝气时间为8 h.通过高、低氨氮浓度（245.28 mg/L与58.08 mg/L）交替进水的方式,经过57个周期（36 d）的稳定运行成功实现...     

还原-ZPF催化氧化降解2,4-DNT效果及其机制

以实验室制备的α-FeOOH柱撑人造沸石（zeotileartificial pillared byα-FeOOH,ZPF）为催化剂,并利用FTIR与XRD技术进行表征,采用批式实验研究其催化H2O2氧化去除地下水中难降解有机污染物2,4-二硝基甲苯（2,4-DNT）的效能,对比分析不同pH条件下Fe0还原、ZPF催化...